Select * from v$sessions.
or
select 'Alter System kill session ' || '''' || sid || ',' || serial# || ''':' || from v$sesion where username='NameOfUserWhoseSessionNeedsToBeKilled'
or
select 'Alter System kill session ' || '''' || sid || ',' || serial# || ''':' || from v$sesion where username='NameOfUserWhoseSessionNeedsToBeKilled'